期刊
PROGRESS IN REACTION KINETICS AND MECHANISM
卷 40, 期 3, 页码 201-248出版社
SAGE PUBLICATIONS LTD
DOI: 10.3184/146867815X14297237081532
关键词
catalysis; unpaired electrons; radicals; matrix isolation; spin-trapping; TiO2; water oxidation; water splitting; graphene; graphene oxide; hydrocarbon conversions; ionic liquids; fuel cells; muon; muonium; enzymes; ESR; EPR; dendrimer; dendron; zeolite; spin-relaxation
Recent progress is surveyed in regard to the importance of molecular species containing unpaired electrons in catalytic systems, as revealed using ESR spectroscopy. The review begins with studies of enzymes and their role directly in biological systems, and then discusses investigations of various artificially created catalysts with potential human and environmental significance, including zeolites. Among the specific types of catalytic media considered are those for photocatalysis, water splitting, the degradation of environmental pollutants, hydrocarbon conversions, fuel cells, ionic liquids and sensor devices employing graphene. Studies of muonium-labelled radicals in zeolites are also reviewed, as a means for determining the dynamics of transient radicals in these nanoporous materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据