期刊
PROGRESS IN ORGANIC COATINGS
卷 79, 期 -, 页码 1-7出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2014.09.017
关键词
Nanocoating; Nanocomposite; Titanium dioxide; Poly(carbonate urethane); Cultural heritage
A water dispersed Titanium dioxide/poly(carbonate urethane) nanocomposite was prepared by means of cold mixing of single components via sonication. The work was aimed at achieving a new material with properties suitable for eco-sustainable applications in cultural heritage as protective coating. The nanocomposite water dispersion prepared was subsequently deposited on Petri dish and, after water casting at room temperature, homogeneous, transparent, colourless film samples were obtained. TGA, DSC, DMTA, ATR-FTIR, FESEM and WAXS techniques were then applied in order to investigate the thermal and visco-elastic behaviours along with morphology and structure of the nanocomposite. Moreover, through methylorange decomposition, an azoic dye representative of environmental pollution, a photocatalytic test was set up on nanocomposite film samples assessing that the 1% (wt/wt) content of Titanium dioxide nanoparticles was able to confer self-cleaning ability. Interrelationships among structure, properties and uses in conservation of this kind of nanomaterial were appraised. (C) 2014 Elsevier B.V. All rights reserved.
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