期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 100, 期 3, 页码 867-871出版社
SPRINGER
DOI: 10.1007/s10973-010-0720-1
关键词
Hydrazine precursor; Ultrafine oxide; Autocatalytic decomposition; DSC; TG; XRD
Manganese zinc ferrous fumarato-hydrazinate precursor, Mn0.6Zn0.4Fe2(C4H2O4)(3)center dot 6N(2)H(4) was synthesized for the first time and characterized by chemical analysis, infrared spectral studies, and thermal analysis. Infrared studies show band at 977 cm(-1) indicating bidentate bridging nature of the hydrazine in the complex. Thermogravimetric (TG) studies show two steps dehydrazination followed by two steps total decarboxylation. The precursor on touching with burning splinter undergoes self propagating autocatalytic decomposition yielding ultrafine Mn0.6Zn0.4Fe2O4. XRD studies confirms single phase formation as well as nanosize nature of as prepared Mn0.6Zn0.4Fe2O4. The saturation magnetization of the as prepared Mn0.6Zn0.4Fe2O4 was found to be 31.46 emu gm(-1), which is lower than the reported, confirms the ultrafine nature of the oxide.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据