期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 102, 期 1, 页码 61-64出版社
SPRINGER
DOI: 10.1007/s10973-009-0523-4
关键词
Citrate complexes; Thermodynamic parameters; Isothermal titration calorimetry
资金
- Polish State Committee for Scientific Research [DS/8230-4-0088-9]
Isothermal titration calorimetry has been used to determine the stoichiometry, formation constants and thermodynamic parameters (Delta G (o), Delta H, Delta S) for the formation of the citrate complexes with the Mn2+, Co2+, Ni2+ and Zn2+ ions. The measurements were run in Cacodylate, Pipes and Mes buffer solutions with a pH of 6, at 298.15 K. A constant ionic strength of 100 mM was maintained with NaClO4. The influence of a metal ion on its interaction energy with the citrate ions and the stability of the resulting complexes have been discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据