期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 100, 期 1, 页码 191-198出版社
SPRINGER
DOI: 10.1007/s10973-009-0572-8
关键词
DSC; TGA-FTIR; C80 techniques; Heat flux calorimetry; Kinetic and thermodynamic parameters; MS (EI) spectroscopy; Pericyclic reactions and mechanism; Phenyl azides; Thermal decomposition ion in 'solution phase' and 'solid phase'
资金
- Ministero della Universita e Ricerca
- Progetto di Finanziamento Triennale
The thermal decomposition (TD) of 2-azidophenylmethanol (1), 2-azidobenzenecarbaldehyde (2), 1-(2-azidophenyl)-1-ethanone (3), (2-azidophenyl)(phenyl)methanone (4) and 1-azido-2-nitrobenzene (5) was analysed by DSC, TG and C80 calorimetric techniques under both oxidative and non-oxidative conditions. The TD of these azides in solution is well known to give the corresponding benzoxazoles, generally in good yields, with the exception of azide 1. When both the outcomes from the solid phase and in 'solution phase' TD reactions combined with the results from EI-MS experiments were considered, sufficient information was available to estimate the azides intrinsic molecular reactivity (MIR).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据