期刊
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 97, 期 3, 页码 885-889出版社
SPRINGER
DOI: 10.1007/s10973-009-0156-7
关键词
Activation energy of adsorption; Adsorption capacity; Adsorption kinetics; CO(2) adsorption; Hydrotalcite; Mixed oxide sorbents; Thermogravimetry
The effect of Cu/Al molar ratio on the high-temperature adsorption characteristics of CO(2) on the mixed oxides of Cu-Al hydrotalcite skeletal structure has been studied by thermogravimetry. The Cu/Al molar ratio of the hydrotalcites synthesized was varied between 1.0 and 3.0, and the adsorption temperature ranged from ambient to 600 A degrees C. The hydrotalcite with Cu/Al molar ratio of 2.0 was found to be the most suitable adsorbent for high-temperature CO(2) adsorption, in both the capacity and the rate of adsorption. The activation energy values suggested that the physical adsorption dominates at low temperatures (< 400 A degrees C) and the chemisorption dominates at high temperatures (> 400 A degrees C).
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