期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 45, 期 5, 页码 2762-2769出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jtice.2014.05.030
关键词
Graphene oxide nanoribbon; Unzipping; Exfoliation; Multiwalled carbon nanotube; Two-step Hummers method
资金
- National Science Council of ROC Taiwan [NSC 100-2628-E-007-028-MY2, 101-3113-E-006-010]
- Low Carbon Energy Research Center of National Tsing Hua University
A unique two-step modified Hummers method is developed to unzip and exfoliate multiwalled carbon nanotubes (MWCNTs) into low-defect graphene oxide nanoribbons (GONRs). From the X-ray diffraction (XRD), Raman spectroscopic (RS), X-ray photoelectron spectroscopic (XPS), Fourier transform infrared spectroscopic (FTIR), and transmission electron microscopic (TEM) results, a mechanism involving multilayer-unzipping followed with rapid local peeing-off (i.e., exfoliation) is proposed for this two-step Hummers procedure which provides a guide for obtaining high-quality GONRs. In the two-step procedure, both multilayer-unzipping of MWCNTs and oxidative exfoliation of multilayer GONRs are accelerated by a freshly prepared, concentrated KMnO4 medium. This action reduces the random damage on the basal plane of resultant GONRs, which is commonly found in the ineffective, time-wasting, oxidant-consuming, one-step strategy. Consequently, low-defect GONRs can be efficiently fabricated in this two-step process. (C) 2014 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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