期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 45, 期 2, 页码 481-494出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jtice.2013.06.013
关键词
Methanol synthesis; Zeolite 4A; Water vapor adsorption; Gas-flowing solids-fixed bed reactor; Multi-objective optimization
Since liquid hydrocarbon fuels dominate the transportation sector for the foreseeable future, methanol could potentially be used as a much cleaner fuel than conventional petroleum-based fuels. Thus, development of methanol synthesis process to improve the methanol productivity has attracted increasing attention. This paper describes a steady-state mathematical model of a gas-flowing solids-fixed bed reactor (GFSFBR) with in situ water adsorption for methanol synthesis. Simulation result demonstrates that selective adsorption of water from methanol synthesis in GFSFBR leads to a significant enhancement in methanol production compared to zero solids mass flux condition. The remarkable advantage of GFSFBR over the conventional sorption-enhanced reaction process is the continuous adsorbent regeneration in this system. In the next step, a multi-objective optimization of GFSFBR is performed in order to maximize the methanol production rate and selectivity. Consequently, non-dominated sorting genetic algorithm-II (NSGA-II) is applied as a powerful method to optimize the GFSFBR. Optimization result has shown that there are optimal values of inlet temperature of gas and flowing solid phases, mass flux of flowing solids, flowing solid diameter, and pressure under which the highest methanol production rate and selectivity can be achieved. This paper shows how the concept of in situ water adsorption could be feasible and beneficial for methanol synthesis. (C) 2013 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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