期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 42, 期 1, 页码 132-137出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jtice.2010.03.014
关键词
Heteropolyanions; Hydrocarbons; n-Hexane; Cyclohexane; Cyclohexene; Toluene
The activation of C-H bonds of hydrocarbon over different heteropolycompounds (HPC) HPMo12O40, FePMo12O40 and PMo11FeO39 catalysts was studied. The catalysts were prepared and characterized by several physical techniques (BET, XRD, FTIR, Raman and P-31 MAS NMR) and the catalytic properties evaluated in the temperature range of 250-400 degrees C. This study examined the relation between the acid-base, redox properties of heteropolycompounds and the reaction behavior of various hydrocarbons n-hexane, cyclohexane, cyclohexene and toluene over these catalysts. The results showed that HPC were more active and selective for the oxidation of C-H bond of hydrocarbon and have pronounced catalytic activity which depends on reaction temperatures, nature of oxo metal (Mo, Fe) in the primary structure and counter-ion (H3O+, NH4+, Fe3+). (C) 2010 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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