Voltammetric determination of the neonicotinoid insecticide thiamethoxam using a tricresyl phosphate-based carbon paste electrode

The objective of the work was to investigate the possibility of using a tricresyl phosphate-based carbon paste electrode for the direct voltammetric determination of the neonicotinoid insecticide thiamethoxam. The analyte was determined by differential pulse voltammetry in Britton-Robinson buffer pH 7.0 in the concentration range of 3.72-41.5 mu g mL(-1). The reproducibility of the analytical signal at the 7.29 mu g mL(-1) level was characterized by a relative standard deviation of 1.3 %. The applicability of the developed method was evaluated by determining thiamethoxam in a river water sample and a commercial formulation Actara 25 WG.