期刊
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
卷 82, 期 7, 页码 -出版社
PHYSICAL SOC JAPAN
DOI: 10.7566/JPSJ.82.073703
关键词
(4d)(3) electron; (5d)(3) electron; spin-orbit interaction; L-S coupling; J-J coupling
The effects of a spin-orbit interaction on transition-metal ions of (4d)(3)- and (5d)(3)-based oxides in which three electrons occupy t(2g) orbitals are studied. The amplitude of the magnetic moment of d electrons on the 5d and 4d orbitals is estimated by numerical diagonalization. It is found that the magnetic moment is reduced by the spin-orbit interaction. It is suggested that (4d)(3)- and (5d)(3)-based oxides are located in the middle of the L-S and J-J coupling schemes.
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