期刊
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
卷 80, 期 2, 页码 -出版社
PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.80.023702
关键词
superconductivity; optical reflectivity; electronic structure; first-principles calculation
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
Systematic optical reflectivity measurements were performed on a series of electron-doped layered nitride LixZrNCl superconductors with a variable carrier density. A Drude band grew up with increasing Li doping level x, providing optical evidence of a transition from a band insulator to a metal. The doping variation of the plasma edge exhibited excellent agreement with the results of first-principles calculations. Furthermore, the good agreement among the optical, thermal, and theoretical effective masses highlights the uniqueness of the present materials, indicating that relatively high T-c superconductivity with T-c similar to 15 K can emerge from a light effective mass m* similar to 0.9 m(0) with minimal renormalization.
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