期刊
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
卷 80, 期 8, 页码 -出版社
PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.80.084707
关键词
photoinduced phase transition; neutral-ionic transition; electron-lattice interaction; electron-molecular-vibration coupling
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [19540381, 23540426, 20340101, 23244062]
- NINS program for cross-disciplinary study [NIFS10KEIN0160]
- Grants-in-Aid for Scientific Research [23244062, 19540381, 23540426] Funding Source: KAKEN
For electronic states and photoinduced charge dynamics near the neutral-ionic transition in the mixed-stack charge-transfer complex tetrathiafulvalene-p-chloranil (TTF-CA), we review the effects of Peierls coupling to lattice phonons modulating transfer integrals and Holstein couplings to molecular vibrations modulating site energies. The former stabilizes the ionic phase and reduces discontinuities in the phase transition, while the latter stabilizes the neutral phase and enhances the discontinuities. To reproduce the experimentally observed ionicity, optical conductivity and photoinduced charge dynamics, both couplings are quantitatively important. In particular, strong Holstein couplings to form the highly-stabilized neutral phase are necessary for the ionic phase to be a Mott insulator with large ionicity. A comparison with the observed photoinduced charge dynamics indicates the presence of strings of lattice dimerization in the neutral phase above the transition temperature.
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