Gas sensing properties of semiconducting copper oxide nanospheroids

Monosize spheroidal porous particles of copper oxide were produced by controlled calcination of the copper basic carbonate particles, synthesized by the urea-based homogeneous precipitation process. After characterization by various physical methods, such as SEM, XRD, and FTIR, the copper oxide particles were employed for the fabrication of the gas sensor. The latter was made up of a thick film of copper oxide on alumina plate, having printed interdigitated gold electrodes. Electrical properties of the sensor material were evaluated as a function of the temperature, which indicated its semiconductor behavior. On exposing to ammonia gas, the sensor responded in the form of a decrease in electrical resistance in a reproducible manner. Reproducibility in performance was attributed to the use of monodispersed particles of copper oxide in the fabrication of sensor. (C) 2015 Elsevier B.V. All rights reserved.