期刊
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS
卷 60, 期 12, 页码 1983-2002出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jmps.2012.08.001
关键词
Continuum mechanics; Diffusion; Elasticity; Plasticity; Lithium-ion batteries
资金
- King Fahd University of Petroleum and Minerals in Dhahran, Saudi Arabia through Center for Clean Water and Clean Energy at MIT
- KFUPM [R9-CE-08]
- NSF [019646-001]
- Div Of Civil, Mechanical, & Manufact Inn
- Directorate For Engineering [1063626] Funding Source: National Science Foundation
We develop a unified framework of balance laws and thermodynamically consistent constitutive equations which couple Cahn-Hilliard-type species diffusion with large elastic-plastic deformations of a body, and account for the swelling and phase segregation caused by the diffusing species. A potential, technologically important, area of application of the theory is in the chemo-mechanical analysis of the evolution of large stresses which develop because of the volume changes associated with the diffusion of lithium ions in the active electrode particles of lithium-ion batteries during charge-discharge cycles. (C)2012 Elsevier Ltd. All rights reserved.
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