Influence of biocorrosion on microstructure and mechanical properties of deformed Mg-Y-Er-Zn biomaterial containing 18R-LPSO phase

The microstructure and mechanical properties of as-extruded Mg-8Y-1Er-2Zn (wt%) alloy containing long period stacking ordered (LPSO) phase are comparatively investigated before and after corrosion in a simulated body fluid (SBF) at 37 degrees C. The as-extruded alloy consists of a long strip-like 18R-LPSO phase and some fine lamellae grains formed by primary recrystallization during the extrusion process. The hydrogen evolution volume per day fluctuates between 0.21 and 0.32 ml/cm(2) in the immersion test for 240 h, and the corresponding corrosion rate is calculated as 0.568 mm/y. The corrosion product is determined as Mg(OH)2, whilst a Ca(H2PO4)(2) compound is also observed on the surface of the samples. The corrosion site preferentially occurs at the interface between LPSO phase and Mg matrix. Before immersing, the tensile yield strength (TYS), ultimate tensile strength (UTS) and elongation of the alloy are 275 MPa, 3.59 MPa, and 19%, respectively. More attractively, these mechanical properties can be maintained even after immersing in SBF for 240 h (TYS, UTS and elongation are 216 MPa, 286 MPa and 6.8%, respectively) because of the existence of high anti-corrosion LPSO phase. (c) 2013 Elsevier Ltd. All rights reserved.