Large E-field induced strain and polar evolution in lead-free Zr-doped 92.5%(Bi0.5Na0.5)TiO3-7.5%BaTiO3 ceramics

Structure, dielectric permittivity, strain, electric (E) polarization, and piezoelectric responses of (Bi1/2Na1/2)(0.925)Ba-0.075(Ti1-xZrx)O-3 (BNT7.5BT-100xZr; x= 0-0.04) ceramics were investigated as functions of poling E field and temperature. The BNT7.5BT ceramic reveals a phase transition from P4bm nanodomains to long-range-ordered P4mm domains. The Zr-doped BNT7.5BT ceramic reveals a reversible change of unit cell with dynamically fluctuating polar nanoregions, which are responsible for the large strain. The poled BNT7.5BT ceramic displays a depolarization temperature of T-d = 90 degrees C, which correspond to a phase transition from ferroelectric to relaxor states. The Zr-doped BNT7.5BT ceramics have Burns temperatures (TB) in the region of 400-435 degrees C, below which polar nanoregions begin to develop. The Zr-doped BNT7.5BT ceramics display wide diffuse phase transitions, suggesting a transition from R + T to T phases. BNT7.5BT-2Zr ceramic shows a temperature dependent linear large strain of 0.482% at 150 degrees C and can be a potential candidate for lead-free actuator. (C) 2014 Elsevier Ltd. All rights reserved.