期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 30, 期 3, 页码 737-742出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2009.08.024
关键词
Dielectric properties; Perovskites; Sintering
资金
- CSIC [PIF MAGIN]
- CICYT [MAT2007-66845-C02-01]
CaCu3Ti4O12 (CCTO) ceramics have been processed by solid state reaction and sintered at 1100 degrees C for different times. A clear increase of the dielectric constant of the material up to values of 6 x 10(4) has been observed with the sintering time. This increase is accompanied by a limited grain growth and intergranular Cu-oxide phase thickness reduction. The disappearance of the Cu-oxide phase is caused by the incorporation of Cu cations into the grains, contributing to the increase of the dielectric constant. Raman spectroscopy shows the decrease of TiO6 octahedral rotational modes with the sintering time due to the incorporation of Cu cations into the CCTO grains. XANES measurements show that the Cu main oxidation state is Cu2+ and does not change with the sintering time. The fitting of the experimental dielectric constant to the Internal Barrier Layer Capacitance (IBLC) model reveals the change of the intergranular phase dielectric constant, caused by a compositional change due to the incorporation of Cu into the CCTO grains. (C) 2009 Elsevier Ltd. All rights reserved.
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