4.6 Article

Beyond 1.0 W cm(-2) Performance without Platinum: The Beginning of a New Era in Anion Exchange Membrane Fuel Cells

期刊

JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 165, 期 15, 页码 J3039-J3044

出版社

ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0071815jes

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资金

  1. US DOE Early Career Program [DE-SC0010531]
  2. UK's Engineering and Physical Sciences Research Council (EPSRC) [EP/M014371/1]
  3. Nancy & Stephan Grand Technion Energy Program (GTEP)
  4. European Union's Horizon 2020 research and innovation program [721065]
  5. Ministry of Science, Technology & Space of Israel through the M. Era-NET Transnational Call 2015, NEXTGAME project [3-12940]
  6. Ministry of Science, Technology & Space of Israel [3-12948]
  7. Israel Science Foundation (ISF) [1481/17]
  8. 2nd Israel National Research Center for Electrochemical Propulsion (INREP2-ISF)
  9. Ministry of National Infrastructure, Energy and Water resources of Israel [3-13671]
  10. EPSRC [EP/M014371/1] Funding Source: UKRI

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This work reports a high power, stable, completely Pt-free anion exchange membrane fuel cell (AEMFC) comprised of highly active catalysts - Pd-CeO2/C at the anode and PdCu/C alloy at the cathode for the hydrogen oxidation and oxygen reduction reactions, respectively. The resulting AEMFC shows outstanding performance, reaching a peak power density of 1 W cm(-2), twice the value of the best performance for Pt-free cells reported in the literature to date. The AEMFC also shows a low voltage degradation rate when operated continuously for more than 100 h at a constant 0.5 A cm(2), with a voltage degradation rate of only 2.5 mV h(-1), which is excellent when compared to nearly all of the AEMFCs reported in the literature to date. This combination of high performance and high stability in the absence of Pt-based catalysts represents a significant landmark in the progress of the AEMFC technology. (C) The Author(s) 2018. Published by ECS.

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