期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 160, 期 6, 页码 A832-A837出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.085306jes
关键词
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资金
- WCU (World Class University) program through the Korea Science and Engineering Foundation
- Ministry of Education, Science and Technology [R31-10022]
- National Research Foundation of Korea [R31-2012-000-10022-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Graphene was used to form efficient conducting networks and to suppress the formation of a solid-electrolyte interface layer, in a sandwiched composite with LiNi0.5Mn1.5O4 (LNMO), which resulted in an improvement in rate capability and coulombic efficiency, respectively. The interaction between the LNMO particles and the residual oxygen functionalities on the basal plane of graphene in solution spontaneously produced LNMO particles that were sandwiched by the graphene. This configuration provided LNMO with less polarization due to higher electronic conductivity, which contributed to an increased rate capability. The graphene-sandwiched LNMO also enhanced a coulombic efficiency due to the suppression of continuous electrolyte decomposition, which eventually resulted in improved capacity retention. Unlike this graphene-sandwiched LNMO, a simple mixture of LNMO with graphene did not show noticeable improvements in rate capability due to a lack of efficient conducting network. A LiMn2O4/graphene composite prepared using the same procedure showed no improvement in coulombic efficiency and, thus, capacity retention was similar to graphene-free LiMn2O4, indicating that the graphene-sandwiching is an effective strategy for high-voltage cathode materials. (C) 2013 The Electrochemical Society. All rights reserved.
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