期刊
POLYMER CHEMISTRY
卷 6, 期 28, 页码 5003-5008出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5py00570a
关键词
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资金
- University of Auckland Faculty Research Development Fund (FRDF)
- University of Auckland Faculty Research Development Fund (FRDF), Materials Accelerator and current Product Accelerator programme from the New Zealand Ministry of Business, Innovation and Employment (MBIE)
Copolymer's properties are controlled not only by co-monomers' composition but also their sequence distribution along the chain. We hereby report a strategy to the synthesis of perfectly alternating PIMs copolymer, an important class of material for gas separation membrane. We achieve this copolymer microstructure through two-pot synthesis process via ABA trimer intermediate. For comparison, both alternating and statistical copolymers with same composition were prepared and characterized with H-1 and C-13 NMR, FT-IR, MALDI-ToF, GPC, TGA, DSC and WAXD. The present work offers new method for repeating unit sequence control in step growth polymerization system.
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