期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 158, 期 5, 页码 A453-A457出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3560205
关键词
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资金
- Ministry of Education, Science and Technology [R31-10013]
- Research Center for Energy Conversion and Storage
A comparative study is made on the surface film formation on the high-voltage LiNi0.5Mn1.5O4 positive electrode at elevated temperature (55 degrees C) in two different electrolytes; LiPF6/organic carbonate and LiTFSI/ionic liquid (propylmethylpyrrolidinium bis(trifluoromethylsulfonyl)imide, PMPyr-TFSI). The surface film derived by a decomposition of the former electrolyte is enriched by inorganic fluorinated species, which becomes thicker with cycling to lead a continued electrode polarization and cell failure. In contrast, organic carbon species are dominant in the film derived from the latter electrolyte. This organic-rich film deposited in the earlier period of cycling seems to effectively passivate the positive electrode presumably due to uniform coverage. As a result, the film does not grow with cycling and electrode polarization is not serious to give a stable cycling behavior. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3560205] All rights reserved.
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