4.6 Article

Carbon Nanotubes Grown on Nanoporous Alumina Templates/Aluminum Foil for Electrodes of Aluminum Electrolytic Capacitors

期刊

JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 157, 期 2, 页码 A237-A241

出版社

ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3272640

关键词

alumina; aluminium; carbon nanotubes; chemical vapour deposition; electrodes; electrolytic capacitors; nanofabrication; nanoporous materials; sputter deposition

资金

  1. National Science Council of the Republic of China [NSC97-2622-E-224-008-CC3]

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Carbon nanotubes (CNTs) were directly grown on nanoporous alumina templates/aluminum foil by chemical vapor deposition using different temperatures and times. Next, aluminum was sputtered onto the nanoporous alumina templates with grown CNTs/aluminum foil with grown CNTs by varying the sputtering time and power. Finally, aluminum oxide was formed by anodizing in an ammonium adipate solution. A higher capacitance (2159 mu F/cm(2)) as well as a superior operation voltage (55.10 V) with the pore bottom of the alumina templates as a substrate and a higher capacitance (3426 mu F/cm(2)) as well as a superior operation voltage (38.44 V) with an aluminum foil substrate were obtained at better/the best CNT growing conditions (600 degrees C/60 min) and better sputtering conditions (65 W and 4 h). Furthermore, the higher the CNT growing temperature, the higher the capacitance. The capacitance decreased with increasing sputtering power and time, but the operation voltage increased with increasing sputtering power and time.

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