期刊
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
卷 60, 期 7, 页码 907-914出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.201300160
关键词
Gold; Copper; Bimetallic; Acetylene hydrogenation; Nanoparticle
资金
- National Science Council, Taiwan
Copper has been reported to be active in selective hydrogenation of acetylene but very selective to oligomers instead of ethylene. In this work, SBA-15 supported Cu-Au bimetallic nanoparticles are studied under different Cu/Au ratios and temperature. The addition of gold promotes the catalytic performance, reducing the amount of oligomers formed on the catalyst's surface. A synergistic effect between copper and gold is also displayed. The bimetallic catalyst with Cu/Au ratio at 1/3 has both better conversion and selectivity between 160-200 degrees C, providing the opportunities to lower the operating temperature (>200 degrees C) of copper. The synergy can be ascribed to the compromise of two factors: the electronic effect and the sintering resistance of bimetallic nanoparticles. Gold makes copper more electron-deficient, therefore, enhances the conversion. Besides, the particles remain highly dispersed and small (ca. 3 nm) when large amount of gold reduces the ensemble size of copper on the surface, minimizing C-C coupling reactions.
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