期刊
POLYMER
卷 66, 期 -, 页码 67-75出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2015.04.020
关键词
Polynorborene; Triarylborane; Iridium
Vinyl-type polynorbornene copolymers (P1-P3) containing side-chain triarylborane and iridium moieties were prepared by palladium(II) catalyzed copolymerization of norbornene monomers bearing triarylborane (Mes(2)BPh, M1) and an iridium emitter ((ppy)(2)Ir(acac), ppy = 2-phenyl-pyridinato-C-2,N; acac = acetylacetonato, M2). Copolymerization led to facile incorporation of the comonomers in a controlled manner depending on the feed ratio of the comonomers (4.0 mol%-Ir in P1; 6.7 mol%-Ir in P2; 12.4 mol%-Ir in P3). While solution PL spectra of the copolymers exhibited partial intra-chain energy transfer from the borane moiety to iridium, complete energy transfer occurred in the rigid matrix, such as at 77 K and in the film state. The LUMO level of the borane moiety (M1) was estimated to be 2.4 eV, which is lower than that of M2 and poly(N-vinylcarbazole) (PVK) (ca. 2.2 eV for both). Solution processed PhOLEDs (D1-D3) incorporating P1-P3 as an emissive material in the PVK host displayed good performance in the low current density region, but D1-D3 suffered severe efficiency roll-off with increasing current densities. Comparable performance of 02 with the device (D4) based on P2 emitter and PVK:PBD (2-(4-biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole) host suggested that a borane moiety in the emissive polymer chain plays an actual role in facilitating electron transport in the emissive layer. (C) 2015 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据