期刊
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
卷 23, 期 10, 页码 1783-1788出版社
SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0103-50532012005000046
关键词
Penicillium citrinum; marine-derived fungus; mixed biosynthesis; dihydropyrrole
资金
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2009/51199-6, 2010/05100-5]
- CNPq [142116/2009-2]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [10/05100-5] Funding Source: FAPESP
Feeding experiments with C-13-labeled precursors were performed in order to establish the biosynthesis of two N-acylated dihydropyrroles, (8E)-1-(2,3-dihydro-1H-pyrrol-1-yl)-2- methyldec-8-ene-1,3-dione (1) and 1-(2,3-dihydro-1H-pyrrol-1-yl)-2- methyldecane-1,3-dione (2), isolated from the cultures of a marine-derived Penicillium citrinum. The biosynthesis of both, 1 and 2, involves the incorporation of acetate, methionine and ornithine.
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