期刊
POLYHEDRON
卷 100, 期 -, 页码 359-372出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2015.08.013
关键词
Ligand design; Crystal structure; Coordination polymers; MOFs; Alkali metals
资金
- Centre National de la Recherche Scientifique (CNRS)
- Ministere de la Recherche (FRANCE)
The reactions of two aroylhydrazone ligands H2Ls and H2LAc with alkaline Li(I), Na(I), K(I) and Ba(II) metal ions afforded nine new coordination polymers with different dimensionalities. These illustrate the ionic radii, the ligand substitution and the solvent influence on the formation of the final product. Interestingly, one of them shows porous structure with a 40% unoccupied volume. (C) 2015 Elsevier Ltd. All rights reserved.
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