期刊
POLYHEDRON
卷 97, 期 -, 页码 66-74出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2015.05.018
关键词
Trifluoromethylphenyl porphyrin; Photophysical properties; Crystal structure analysis; Hirshfeld surface analysis; Antimicrobial studies
资金
- Department of Science and Technology (DST), India [SR/WOS-A/CS-146/2011, SR/FT/CS-25/2011, SB/EMEQ-016/2013]
We have reported the synthesis, spectral and anti-microbial studies of 5,10,15,20-tetrakis(4'-trifluoromethylphenyl)porphyrin derivatives, MT(4'-CF3P)Ps where M = 2H, 1; Fe(II), 2; Ni(II), 3; Cu(II), 4; Zn(II), 5 and Pt(II), 6. The optical absorption and steady state fluorescence spectra of 1-6 show characteristic bands comparable with MTPPs. Compounds 1 and 3-5 were structurally characterized using single crystal X-ray diffraction analysis; 1 and 4 crystallized in the triclinic system, whereas 3 and 5 in the monoclinic system. The high spin nickel(II) ion in 3 is well placed at the center of the planar porphyrin core, which is influenced by the presence of trifluoromethylphenyl groups at the periphery and two THF molecules in apex positions. The porphyrins I and 3-5 are arranged in a slip-stacked fashion involving C-H center dot center dot center dot pi and C-F center dot center dot center dot H-(sol) intermolecular close contacts for 1, 4 and 3, 5, respectively. The role of non-covalent interactions involving the trifluoromethylphenyl groups in the crystal packing have been analyzed and quantified using Hirshfeld surface analysis. The antimicrobial activity of the free ligand is higher compared to its metal complexes. (C) 2015 Elsevier Ltd. All rights reserved.
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