期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 40, 页码 12765-12769出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b09425
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资金
- ICIQ
- MINECO [CTQ2015-65496-R, SEV-2013-0319]
- MINECO
- La Caixa
A mild, chemo- and site-selective catalytic protocol that allows for incorporating an alkylboron fragment into unactivated olefins is described. The use of internal olefins enables C-C bond-formation at remote sp(3) C-H sites, constituting a complementary and conceptually different approach to existing borylation techniques that are currently available at sp(3) centers.
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