期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 42, 页码 13562-13565出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b08197
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [JP17H05164, JP18H02051, JP17K19164, 16J02975]
- Iketani Science and Technology Foundation
- Mitsubishi Foundation
- Sumitomo Foundation
A corannulene possessing two B-N units on the spoke, 10b(1),18b(1)-diaza-10b,18b-diboratetrabenzo [a,g,j,m]corannulene, was synthesized on a multigram scale in four steps from commercially available compounds. Its shallow bowl-shaped structure was confirmed by X-ray crystallography. The B2N2-embedded corannulene showed strong blue fluorescence and was employed as an efficient emitter for an organic light-emitting diode.
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