期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 37, 页码 11618-11622出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b08282
关键词
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资金
- National Natural Science Foundation of China [51603114]
- Natural Science Foundation of Shandong Province [ZR2016EMQ03]
- Science and Technology Foundation of Qingdao City [16-5-1-43-jch]
- Doctorial Fund of Qingdao Agriculture University [663-1115046, 663-1117016, 663-1113309]
- Ocean University of China
A C-3-symmetric benzotrithiophene tricarbaldehyde (BTT) is synthesized for the first time with a facile method, which is used to construct BTT-based covalent organic frameworks (COFs) with different pore sizes. Meanwhile, the structure transformations of the COFs under high-temperature ionothermal condition are studied systematically, and the relationships between the regularly changed structures of the further-cross-linked COFs and their supercapacitor performances are investigated. It turns out that dealing with COFs of designated structures under ionothermal condition is a great method to build highly conductive structure-controllable materials for electrochemical applications.
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