期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 32, 页码 10075-10079出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b04266
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资金
- NIH [1R01GM111486-01A1]
- NSF [CHE 1625543]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM111486] Funding Source: NIH RePORTER
Six directed hydrogen bonding (H-bonding) interactions allow for the reversible capture and reduction of dioxygen to a trans-1,2-peroxo within a tripodal zinc(II) framework. Spectroscopic studies of the dizinc peroxides, as well as on model zinc diazides, suggest H-bonding contributions serve a dominant role for the binding/activation of these small molecules.
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