期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 32, 页码 10135-10139出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b06565
关键词
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资金
- Office of Naval Research [N00014-17-1-2205]
- Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, U.S. Department of Energy (DOE) [DE-FG02-01ER15264]
We describe here the direct connection between the molecular conformation of a conjugated macrocycle and its macroscopic charge transport properties. We incorporate chiral, helical perylene diimide ribbons into the two separate macrocycles as the n-type, electron transporting material. As the macrocycles' films and electronic structures are analogous, the important finding is that the macrocycles' molecular structures and their associated dynamics determine device performance in organic field effect transistors. We show the more flexible macrocycle has a 4-fold increase in electron mobility in field effect transistor devices. Using a combination of spectroscopy and density functional theory calculations, we find that the origin of the difference in device performance is the ability of more flexible isomer to make intermolecular contacts relative to the more rigid counterpart.
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