期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 140, 期 34, 页码 10677-10681出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b06432
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资金
- Alexander von Humboldt Foundation
We report a chiral phosphoric acid catalyzed bromocyclization/regiodivergent reaction of racemic intermediates sequence, which is enabled by anchimeric oxygen borrowing. Different types of alkenes are applicable, and both enantiomers of the bromohydrin products were obtained in generally excellent yields and enantioselectivities. In addition, an example of enantioconvergent synthesis from the two isomeric products is presented.
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