期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 8, 页码 3013-3015出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja500118w
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资金
- 973 Program [2012CB821600]
- NSFC [21332002, 21272010, 21172005]
A Rh(I)-catalyzed formal carbene insertion into C-C bond of benzocyclobutenols has been realized by employing diazoesters as carbene precursors. The product indanol derivatives were obtained in good yields and in diastereoselective manner under mild reaction conditions. All-carbon quaternary center is constructed at the carbenic carbon. This catalytic reaction involves selective cleavage of C-C bond, Rh(I) carbene insertion, and intramolecular aldol reaction.
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