期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 39, 页码 13506-13509出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja506532h
关键词
-
资金
- Eli Lilly
- National Institute of Health [R01NS045684]
- National Science Foundation under the CCI Center for Selective C-H Functionalization [CHE-1205646]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1205646] Funding Source: National Science Foundation
The synthesis of 1,2-diamines has been achieved through a single-step, tandem sequence involving Rh-catalyzed aziridination followed by NaI-promoted rearrangement to an isomeric cyclic sulfamide. Facile ring opening of these products in hot water and pyridine affords differentially protected vicinal diamines. Demonstration of the utility of this method for the syntheses of (+/-)-enduracididine and (+/-)-allo-enduracididine is highlighted.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据