期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 16, 页码 5912-5915出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja502601g
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资金
- MEXT
- ACT-C program of the JST
- Grants-in-Aid for Scientific Research [23350041, 22105005] Funding Source: KAKEN
C-C and C-Si sigma-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.
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