期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 40, 页码 13942-13958出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja507807v
关键词
-
资金
- NRF of Korea through CRI [NRF-2012R1A3A2048842]
- GRL [NRF-2010-00353]
- German Deutsche Forschungsgemeinschaft (Cluster of Excellence Unifying Concepts in Catalysis) [314/1]
- Cost Action [CM130S ECOSTBio]
- National Research Foundation of Korea [2012R1A3A2048842, 2010-00353] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Selective functionalization of unactivated C-H bonds, water oxidation, and dioxygen reduction are extremely important reactions in the context of finding energy carriers and conversion processes that are alternatives to the current fossil-based oil energy. A range of metalloenzmes achieve these challenging tasks in biology by using cheap and abundant transition metals, such as iron, copper, and manganese. High-valent metal-oxo and metal-dioxygen (superoxo, peroxo, and hydroperoxo) cores act as active intermediates in many of these processes. The generation of well-described model compounds can provide vital insights into the mechanisms of such enzymatic reactions. This perspective provides a focused rather than comprehensive review of the recent advances, in the chemistry of biomimetic high-valent metal-oxo and metal-dioxygen complexes, which can be related to our understanding of the biological systems.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据