期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 11, 页码 4133-4136出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja500712z
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资金
- Princeton University
- Natural Sciences and Engineering Research Council of Canada
A family of pincer-ligated cobalt complexes has been synthesized and are active for the catalytic C-H borylation of heterocycles and arenes. The cobalt catalysts operate with high activity and under mild conditions and do not require excess borane reagents. Up to 5000 turnovers for methyl furan-2-carboxylate have been observed at ambient temperature with 0.02 mol % catalyst loadings. A catalytic cycle that relies on a cobalt(I)-(III) redox couple is proposed.
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