期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 7, 页码 2905-2910出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja500076h
关键词
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资金
- National Science Foundation of China (NSFC) [51102173, 51272164, 51372195, 51332003]
- Sichuan University [2082204144033]
- Fundamental Research Funds for the Central Universities [2012SCU04A01]
Environment protection and human health concern is the driving force to eliminate the lead from commercial piezoelectric materials. In 2004, Saito et al. [Saito et al., Nature, 2004, 432, 84.] developed an alkali niobate-based perovskite solid solution with a peak piezoelectric constant d(33) of 416 pC/N when prepared in the textured polycrystalline form, intriguing the enthusiasm of developing high-performance lead-free piezoceramics. Although much attention has been paid on the alkali niobate-based system in the past ten years, no significant breakthrough in its d(33) has yet been attained. Here, we report an alkali niobate-based lead-free piezoceramic with the largest d(33) of similar to 490 pC/N ever reported so far using conventional solid-state method. In addition, this material system also exhibits excellent integrated performance with d(33)similar to 390-490 pC/N and T-C similar to 217-304 degrees C by optimizing the compositions. This giant d(33) of the alkali niobate-based lead-free piezoceramics is ascribed to not only the construction of a new rhombohedral-tetragonal phase boundary but also enhanced dielectric and ferroelectric properties. Our finding may pave the way for lead-free at last.
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