期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 44, 页码 15509-15512出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5095342
关键词
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资金
- MEXT
- JST
- JSPS Research Fellowship for Young Scientists
- Grants-in-Aid for Scientific Research [14J03693, 22105002, 22105001] Funding Source: KAKEN
Oxidative coupling between C((sp2)))-H bonds and C((sp3)))-H bonds is achieved by the Ni(II)-catalyzed reaction of benzamides containing an 8-aminoquinoline moiety as the directing group with toluene derivatives in the presence of heptafluoroisopropyl iodide as the oxidant. The method has a broad scope and shows high functional group compatibility. Toluene derivatives can be used as the coupling partner in an unreactive solvent.
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