期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 19, 页码 6786-6789出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja500362w
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资金
- NRF of Korea [NRF-2012-R1A2A2A01045064]
- Ministry of Education [NRF-2009-0094023]
- Agency for Defense Development through Chemical and Biological Defense Research Center
This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.
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