期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 38, 页码 13178-13181出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja507902z
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资金
- U.S. National Science Foundation (NSF) [CHE-1265988]
- NSF [DGE-1148900]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1265988] Funding Source: National Science Foundation
Planar, low-spin cobalt(II) dialkyl complexes bearing bidentate phosphine ligands, (P-P)Co-(CH2SiM3)(2), are active for the hydrogenation of geminal and 1,2-disubstituted alkenes. Hydrogenation of more hindered internal and endocyclic trisubstituted alkenes was achieved through hydroxyl group activation, an approach that also enables directed hydrogenations to yield contrasteric isomers of cyclic alkanes.
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