期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 26, 页码 9264-9267出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja504228p
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资金
- NIH [GM-59417]
An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that the process represents a method for the stereoselective directed dihydroxylation of alkenes.
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