期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 2, 页码 650-652出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja412277z
关键词
-
资金
- Singapore National Research Foundation [NRF-RF2008-10]
- Nanyang Technological University
The asymmetric intermolecular Heck reaction has been limited to aryl and vinyl triflates. Herein, we extend the reaction to aryl and vinyl bromides. Various cyclic olefins coupled with high enantioselectivity. Only bisphosphine oxides on a Spiro backbone formed highly stereoselective Pd catalysts. The use of alcoholic solvents and alkylammonium salts were essential to promote halide dissociation from neutral arylpalladium complexes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据