期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 42, 页码 14734-14737出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja5088584
关键词
-
资金
- National Institute of General Medical Sciences of the National Institutes of Health [GM 084333]
The first highly diastereo- and enantioselective additions of a halogen and phosphoramidic acid to unactivated alkenes have been developed, catalyzed by a chiral Bronsted acid. A unique feature of these additions is the opportunity for stereocontrol at two noncontiguous chiral centers, carbon and phosphorus, leading to cyclic P-chiral phosphoramidates. In addition to their inherent value, the phosphoramidates are precursors to enantioenriched epoxy allylamines.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据