期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 19, 页码 6778-6781出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4131774
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资金
- National Science Foundation [DMR-1104650]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1408834] Funding Source: National Science Foundation
Ag(I) is used to form a pi-stacked metal- organic solid that exhibits remarkably high electrical conductivity. The solid undergoes a single-crystal-to-single-crystal [2+2] photodimerization to generate a 1D coordination polymer with over 40% higher conductivity. The Ag(I) complex represents the first example of an increase in conductivity resulting from a [2+2] photodimerization. Density of states calculations show a higher contribution from Ag(I) ions to the valence band in the photodimerized solid, supporting the increase in conductivity.
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