期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 4, 页码 1218-1221出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4113462
关键词
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资金
- University of Michigan
- Alfred P. Sloan Foundation
- Camille and Henry Dreyfus Foundation
- American Chemical Society Division of Organic Chemistry
- Amgen
- Vertex
The development of a room-temperature lignin degradation strategy consisting of a chemoselective benzylic oxidation with a recyclable oxidant ([4-AcNH-TEMPO]BF4) and a catalytic reductive C-O bond cleavage utilizing the photocatalyst [Ir(ppy)(2)(dtbbpy)]PF6 is described. This system was tested on relevant lignin model substrates containing beta-O-4 linkages to generate fragmentation products in good to excellent yields.
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