4.8 Article

1,2-Boryl Migration Empowers Regiodivergent Synthesis of Borylated Furans

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 38, 页码 13146-13149

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ja507054j

关键词

-

资金

  1. National Institutes of Health [GM-64444]
  2. National Science Foundation [CHE-1362541]

向作者/读者索取更多资源

A regioselective transition metal-catalyzed cycloisomerization reaction of boron-containing alkynyl epoxides toward C2- and C3-borylated furans has been developed. It was found that the copper catalyst as well as the gold catalyst with more basic triflate counterion favor boryl migration toward C3-borylated furans, whereas employment of the cationic gold hexafluoroantimonate affords C2-borylated furan via a formal 1,2-hydrogen shift.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据