期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 136, 期 9, 页码 3350-3353出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja412197j
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资金
- MEXT [24685018]
- Foundation for Interaction in Science Technology
- Grants-in-Aid for Scientific Research [24685018] Funding Source: KAKEN
We achieved optical resolution of 4,7,12,15-tetrasubstituted [2.2]paracyclophane and subsequent transformation to planar chiral building blocks. An optically active propeller-shaped macrocyclic compound containing a planar chiral cyclophane core was synthesized, showing excellent chiroptical properties such as high fluorescence quantum efficiency and a large circularly polarized luminescence dissymmetry factor.
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